BoilingPoint:85-6°

EINECSNumber:212-104-5

MolecularWeight:114.26

SpecificGravity:0.7193

Flashpoint:7°C(45°F)

HMISKey:2-4-0-X

Formula:C₆H₁₄Si

RefractiveIndex:1.4074

TSCA:TSCA

Application:Keyreviews.^1,2,3,4
Carriesoutdeoxygenativeallylationofbenzylicalcohols.¹⁰
Allylateslithiumalkoxidesw/lossofthelithiumoxide.¹¹
Formsbenzylichomoallylicalcoholsina3-componentreactionw/aldehydes.¹²
Diallylatesketonesviatheirketals.¹³
Undergoespolymerizationwithzirconocenecomplexes.⁵
Providesfunctionalterminationoflivingcarbocationicpolymerizedpolyisobutylenes.⁶
Allylatesdioxolanes.⁷
Allylatesiminesunderfluoridecatalysis.⁸
Providesalternativefortheformationoftrans-allyl-2,3-O-isopropylidene-protectedpyrrolidines.⁹

Reference:1. HandbookforReagentsforOrganicSynthesis,ReagentsforSilicon-MediatedOrganicSynthesis,Fuchs,P.L.Ed.,JohnWileyandSons,Ltd.,2011,p.14-24.
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12. Kataki,D.;Phukan,P.TetrahedronLett.2009,50,1958.
13.Galy,N.etal.Tetrahedron2011,67,1448.
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Fieser:

AdditionalProperties:Versatilesynthon-transfersallylgroup,highlynucleophilicdoublebond