BoilingPoint:128-9°/0.03
EINECSNumber:220-569-0
MeltingPoint:41-3°
MolecularWeight:304.91
AlternativeName:TRIPHENYLGERMANIUMHYDRIDE
HMISKey:2-1-1-X
Formula:C18H16Ge
RefractiveIndex:1.6187
Application:AddstoepoxidesinpresenceofEt3B.1
CatalystwithCo2(CO)8forpreparationofglycolmonoalkylethersfromsynthesisgas,HCHOandalkanols.2
FormscarbonylrADIcalacceptorsynthonsyieldingcyclopentanones3,oximes.4
Regioselectiveadditiontoalkynesgives(E)vinylgermanes.5
UndergoesH2PtCl6catalyzedhydrogermylationreactions.6
Reference:1.Ichinose,Y.etal.Chem.Lett.1988,8,1437.
2.Knifton,J.J.Mol.Catal.1985,30,281.
3.Curran,D.etal.J.Am.Chem.Soc.1997,119,4797.
4.Iserloh,U.J.Org.Chem.1998,63,4711.
5.Esteruelas,M.A.etal.Organometallics1999,18,2267.
6.Schumann,H.etal.Organometallics2007,26,397.
AdditionalProperties:Dipolemoment:2.60debye
Disproportionatesatelevatedtemperature
