BoilingPoint:74-5°
EINECSNumber:209-833-6
MeltingPoint:-54°
MolecularWeight:178.83
SpecificGravity:1.291
Flashpoint:-12°C(10°F)
HMISKey:3-4-0-X
Formula:C4H12Sn
RefractiveIndex:1.4410
TSCA:TSCA
Application:Reviewed.1
FormstransparentconductiveoxidesforphotovoltaicsbyPECVD.10
Safetyandhandlingconsiderations.11
IncombinationwithWCl6catalyzesolefinmetathesis.2
Allowssynthesisofevennumberedalkanes.3
Convertsacidchloridestomethylketoneswithbenzylchlorobis(triphenylphosphine)pallADIum.4,5
FormsarylmethylketonesfromarylhalidesandCOinthepresenceofdicarbonylbis(triphenylphosphine)nickel.6
ForCVDoftinoxidetransparentconductiveelectrodesonglassforphotovoltaicsandsensors.7
Pyrolyzedinvacuumtotinat600-750°.8
PyrolyzedoxidativelytoSnOat350-600°.9
Reference:1.Scott,W.J.;Jones,J.H.;Moretto,A.F.inEncyclopediaofReagentsforOrganicSynthesis1995,Volume8,4823-4825.
10.Chandra,H.etal.Am.Vac.Soc.2008,55,TFThA10.
11.Kalb,P.etal.ReportBNL-52123,1987OrderNTIS#DE89005936.
2.vanDam,P.etal.J.Chem.Soc.,Chem.Commun.1972,1221.
3.Gibson,T.etal.J.Org.Chem.1981,46,1821.
4.Milstein,D.etal.J.Org.Chem.1979,44,1613.
5.Labadie,J.etal.J.Am.Chem.Soc.1983,105,6129.
6.Tanaka,M.Synthesis1981,47.
7.Inagaki,N.J.Appl.Polym.Sci.1989,37,2341.
8.Svoboda,G.etal.Ind.Eng.Chem.Res.1992,31,19.
9.Borman,C.etal.J.ElectRochem.Soc.1989,136,3820.
AdditionalProperties:Ea
Hcomb:903.5kcal/moleHform
Hvap:6.8kcal/moleSn-Mebonddissociationenergy:227kJ/mole
VaporpressureVaporpressure
