BoilingPoint:78-80°/0.2

EINECSNumber:211-704-4

MolecularWeight:291.05

AlternativeName:TRIBUTYLSTANNANE

SpecificGravity:1.082

Flashpoint:40°C(104°F)

HMISKey:3-2-1-X

Formula:C₁₂H₂₈Sn

RefractiveIndex:1.4731

TSCA:TSCA

Application:Reviewed.¹
Reducesorganichalides.²
Reducesacidchloridestoaldehydes.³
Reducesenoltriflatestoolefins.⁴
Effectspartialreductionsofchlorosilanes.⁵
RateconstantforarylrADIcals:7.8x10⁸M^-1s^-1.⁶
Reductionsreviewed.⁷
ReactswithHfCl4toprovidehafniumhydridespecies,whichreducesaldehydesandketones.⁸

Reference:1.RajanBabu,T.V.inEncyclopediaofReagentsforOrganicSynthesis1995,Volume8,5016-5023.
2.VanDerKerk,G.F&F:Vol.1,p1192;J.Appl.Chem.1937,7,366.
3.Kuivala,H.J.Org.Chem.1961,25,284;J.Am.Chem.Soc.1966,88,571.
4.Scott,W.etal.J.Am.Chem.Soc.Soc.1986,108,3033.
5.Paetzold,U.etal.J.Organomet.Chem.1996,508,147.
6.Garden,S.etal.J.Org.Chem.1996,61,805.
7.Neumann,W.Synthesis1987,665.
8.Shibata,I.etal.Synlett2009,1495.

Fieser:F&F:Vol.1,p.1192;Vol.2,p.424;Vol.3,p.294;Vol.4,p.518;Vol.5,p.685;Vol.6,p.604;Vol.7,p.497,Vol.9,p.476;Vol.10,p.411;Vol.11,p.545;Vol.12,p.516;Vol13,p316;Vol.14,p.312;Vl.15,p.325;Vol.16,p.343;Vol.19,pp.352-359;Vol.21,p.333.

AdditionalProperties:Decomposes>250?
StABIlizedwith50ppmBHTUndergoeshydrostannationreactions;selectivereducingagent
Vaporpressure