BoilingPoint:104-6°/3.5
EINECSNumber:231-291-4
MolecularWeight:317.08
SpecificGravity:1.085
Flashpoint:>110°C(>230°F)
HMISKey:2-2-0-X
Formula:C14H30Sn
RefractiveIndex:1.4776
Application:Reviewed.1
Intermediateforvinyllithiumbyexchangewithphenyllithium.2
WithCOformsdivinylketonesonreactionwithvinyliodides.3
ReactswithIC6H4CHOinDMFwithPdCl2(CH3CN)2toyieldCH2=CHC6H4CHO.4
Reactswithhalopyrimidinestoyieldvinylpyrimidines.5
Employedinone-potsynthesisofpyrroles.6
Reference:1.Scott,W.J.;Moretto,A.F.inEncyclopediaofReagentsforOrganicSynthesis1995,Volume8,5503-5506.
2.Seyferth,D.etal.J.Am.Chem.Soc.1961,83,3583.
3.Goure,W.etal.F&F:Vol.12,p45;J.Am.Chem.Soc.1984,106,6417.
4.Bumagin,N.Chem.Abstr.111,214179;MetalOrg.Chem.1989,2,475.
5.Kondo,Y.etal.Chem.Pharm.Bull.1989,37,2814.
6.Nakamura,M.etal.Org.Lett.1999,1,1505.